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ensors an ens ng ys ems or Machin Mac hine e Olfact Olfaction ion – Ele Electr ctroni onicc Nose and Electronic Tongue Dr. Nabarun Bhattachar a C-DAC, Kolkata . October 29, 2009

Presentation Structure Human Olfaction Machine Olfaction Electronic Nose Design Details and Results

Electronic Tongue Desi De si n Det Detai ails ls an and d Res Resul ults ts

Roadmap for Research in Machine Olfaction Conclusion

.

Human Olfaction The olfactory region is located in the roof of the two nasal cavities  when compounds (called odorants)) that are carried by odorants inhaled air stimulate receptors located in the olfactory epithelium. The mucous lipid , which is pro uce n e o ac ory epithelium,, assists in epithelium transporting the odorant molecules. Only volatile materials that are soluble in the mucous can interact with the olfactory recep ors an pro uces e signals that our brain interprets as odor.

Machine Olfaction  Attempts to mimic mimic human senses senses of smell and taste by electronic means are called machine Olfaction. Sensors are the most crucial components in a machine olfaction system. Signal conditioning, data acquisition, data, data processing and pattern recognition are the crucial modules of an olfactory sensing .

Machine Olfaction System

 Hum  H uman an Pe Perc rcep epti tion on Eye:

V IS IO N

Machine Ma chine Sensing V I SIO N :C a m e r a

ar: S k in :

: T A C T IL E SENSES

c ro p o n e

TOUCH: Tactile  

Devices -

Tongue:TASTE

TASTE: TAS TE: E-T E-Tongu ongue e

About Electronic Nose Electronic Nose senses complex odours using an Array of Sensors (called “sensor array”): each tuned for o our o a am y o vo at e compoun s. Odour stimulus imprints a characteristic electronic . This smell print is statistically classified and resolved with suitable attern reco nition en ine as a measurement of odour of the sample. In short, Electronic Nose is “A scientific, reliable, repeatable, physical, non-invasive, affordable real-time techniques for various applications like food quality assessment, environmental polution detection, medical applications, explosive detection etc.

Basic Block Diagram Odour Delivery System

Sensor Array

Classification

ent cat on

Signal Conditioning

Data Acquisition

our

an

ng

e very

Headspace Sampling  Autosampling Stage  Air 

S1 Mass Flow Controller 

S2

Solenoid Valves

S3

Sensor Cell

Bubbler System

Measurement Circuit

Syringe Needles Liquid Sample

Temperature Controlled Bath

ensors

Desirable Properties of Selectivity : Must respond to a range of chemical

species. Sensitivity : Should be sensitive to detect vapour

. Speed of Response : Response time should be in . Reproducibility : Sensors response characteristics should be reproducible. Reversibility : Should be able to recover immediately after exposure to gas. Portability : Should be small so that less sample volume may be used.

Interface Circuit Diagram 





Each sesnsor is a MOS sensor made from a metal oxide film, e.g., Tin Oxide Volatiles under o redox reactions at the sensor surface, resulting in a chan e of conductivit across the sensor Each sensor is reversible.

Vc

V RL

RL

VH

GND

Measurement Circuit with MOS Sensor

within TTL range.

Signal Conditioning The output of the sensors is analogue voltage. stages,namely,buffering,amplification,filtering,co the USB card used in the system for data acquisition. No additional electronics has been used for this purpose

Data Acquisition Circuit USB 6009 card from the National Instruments has been used. DAQ system consists of sample and , to digital conversion module. Sample rate :250 Ksamples/second

Signal Pre-processing Steps of Signal Pre-processing: Baseline identification and mani ulation Compression

Baseline Handling Baseline refers to sensor response in no exposure condition Fractional techni ue of baseline manipulation is used for compensation a ainst drift and contrast enhancement.

 y s t  =

 x s t  − x s 0  x 0

Compression Technique Compression is a preprocessing stage where the response of sensor array is uti ize as a eature vector or a fingerprint by reducing the number of escriptors. The maximum value vector from the sensor output data has only been considered for data analysis. =

[S i1 max ..............S i8 max ]

Nose…

Olfaction Software

Software features: -Programmable Sequence Control -Dynamic Fermentation Profile Display -Data Logging -Alarm Annunciation - ex y o perm ea p an ers emse ves o ra n an the system as per their requirements.

cus om ze

a a na ys s

 About Sensor Array Output .

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⎢ . ⎢ ⎢ b h1  A = ⎢ S 11

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bh2

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S 12

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b h8 ⎥ S 18 ⎥

S  22

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S  28 ⎥

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⎢ b 21 ⎢ ⎢ . ⎢

⎢ S  21 ⎢ . ⎢ ⎢ . ⎢ . ⎢ ⎢⎣ S m 1

b 22

S m 2

.

.

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⎥ b 28 ⎥ .⎥ ⎥

Sensor responses during headspace generation

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⎥ ⎥

S m 8 ⎥⎦

Sensor responses when exposed to tea odour during sampling

Data is 8-dimensional Headspace Duration : 30 Seconds and Sampling Duration : 50 seconds 10 rea ings are scanne per secon  Approximately 800 rows are there in any sniffing data matrix

Data Analysis Strategy MULTIVARIATE DATA

DATA EXPLORATION

PRINCIPAL COMPONENT ANALYSIS (PCA)

DATA QUANTIFICATION

AROMA SCORE CALCULATION BY 2NORM METHOD

DATA CO-RELATION

AROMA SCORE CALCULATION BY MAHALANOBIS DISTANCE METHOD

BACK PROPAGATION

ARTIFICIAL NEURAL NETWORK

RADIAL BASIS FUNCTION

PROBALISTIC NEURAL NETWORK

Results – Different Clones Well-defined clusters are found in PCA. 100% classification accurac observed in BP-MLP

Electronic Tongue

Tea Liquor 

 Array of

Wate r 

Current Status vis-à-vis Work Plan

11th Plan Project proposed

Pilot Level Deployment

NTRF Funding

Future Scope of Research Hybrid sensor array consisting of MOS, CP Development of new sensor array sensitive Development of more efficient algorithms or e er c us er ng an c ass ca on Techniques for drift compensation Integration of E-Nose with E-Tongue and E-Vision s stems --- ENTV S stem

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