Formulation Isp
Content
2
Table of Contents
1. Overview of HI&I Cleaning Formulary
2. ISP Products & Properties in HI&I Cleaning
3. Hand Soap Formulations
3.10 Liquid Hand Soap
4. Laundry Formulations
4.10 Laundry Pre-spotter
4.11 Laundry Pre-spotter & Stain Remover
4.20 Liquid Laundry Detergent (clear & non-builder)
4.21 Heavy Duty Liquid Laundry Detergent
4.30 Powder Laundry Detergent (Color-Safe)
4.40 Laundry Detergent Tabs (Formula #1)
4.41 Laundry Detergent Tabs (Formula #2)
4.50 Fabric Softener (3 Formulations)
5. Dishwashing Formulations
5.10 Manual Liquid Dishwash Detergent
5.11 Liquid Dishwash Detergent (Formula #1)
5.12 Liquid Dishwash Detergent (Formula #2)
5.15 Ecological Liquid Dishwash Detergent
5.20 Automatic Dishwash Liquid Detergent
5.30 Dishwash Detergent Tabs
5.50 Automatic Dishwash Rinse-Aid (Formula #1)
5.51 Automatic Dishwash Rinse-Aid (Formula #2)
3
6. Household Cleaning Formulations
6.10 Multipurpose Hard Surface Cleaner
6.20 Multipurpose Alkaline Degreaser
6.21 Kitchen Disinfectant Cleaner
6.22 Kitchen Degreaser (Formula #1)
6.23 Kitchen Degreaser (Formula #2)
6.24 Kitchen Degreaser (Formula #3)
6.25 Oven Cleaner
6.26 Kitchen Cleaning Wipes
6.30 Glass Cleaner (Formula #1)
6.31 Glass Cleaner (Formula #2)
6.32 Glass Cleaning Wipes
6.40 Bathroom Cleaner (Formula #1)
6.41 Bathroom Cleaner (Formula #2)
6.42 Toilet Bowl Cleaner
6.50 Floor Cleaner
6.51 Floor Polish (2 Formulations)
6.52 Carpet Cleaner
6.53 Machine Carpet Cleaner
6.55 Silicone Furniture Polish
6.60 Windscreen Cleaner
6.70 Air Freshener (Formula #1)
6.71 Air Freshener (Formula #2 – Poppy Fragrance)
7. Industrial & Institutional Cleaners
7.10 Car Wash Shampoo
7.11 Car Wash & Wax Cleaner
7.12 High Gloss Tire Wax
7.13 Liquid Car Polish
7.20 Alkaline Grill Cleaner
7.30 Metal Cleaner
8. Appendix A: Summary of Chemical Functionalities
4
1. Overview of HI&I Cleaning Formulation Guide
This guide is a collection of HI&I (Household, Industrial & Institutional) cleaning formulations
developed by several ISP scientists over the last 10 years. The main purpose of these
formulations was to prepare and test different types of cleaners in order to measure the
benefits of various ISP specialties in many diverse HI&I applications. Thus, most
formulations were developed and tested to measure specific properties and features, without
any attempt to have a complete evaluation of long-term stability and performance in the
manner that commercial cleaners are tested before introduction to the consumer market.
With this background in mind, this guide is not intended as a comprehensive treatise on the
complex subject of cleaning formulations. Even within a specific cleaning category, the
number of possible formulations is quite extensive due to differences in water conditions,
regional regulations, consumer preferences, performance, affordability, and marketing
strategies. As it is impossible to cover all these combinations, this formulation guide
documents one to three representative formulations for each cleaning category, that in some
cases are specific to the geographic region where the formulation was originally developed
and tested.
This guide can be used as a starting reference tool for sales engineers as well as formulators
that want to examine how ISP specialties are employed in different cleaning formulations. It
is strongly recommended that formulators use many other sources and ideas to develop,
optimize and test their cleaning formulas. Considering the broad nature of cleaning
formulations around the globe, it is quite unlikely that any of the formulations found in this
guide can be used “as is” without any modifications or additional testing. Thus, we
encourage scientists and engineers to use this guide as a starting point in their quest for
better cleaning formulations and products.
This guide was developed as a collective effort with significant contributions from many ISP
scientists around the world. Most of the formulations included in this guide are credited to
the following individuals:
Americas: Frank Fusiak Michael Jurek Purvita Shah
Europe: Jon Virgoe Rob Gibbison J.J. Gulka
Asia-Pacific: Siaw-Ee Loh T.L. Tan
Editor: Sotiri A. Papoulias
5
2. ISP Products, Properties & Functionalities in HI&I Cleaning
ISP Overview ISP is a global supplier of water-soluble chemicals including wetting
agents, solvents, thickeners, dye-transfer inhibitors, disintegrants,
biocides and other specialties marketed to the HI&I market. Most ISP
products are environmentally friendly, biodegradable and thus suitable for
household, industrial & institutional cleaning formulations.
ISP Product
Summaries
A. Environmentally Friendly Solvents
A-1: M-Pyrol
®
(N-methyl pyrrolidone)
♦ Excellent chemical stability
♦ High boiling point (202°C)
♦ Good solvency
B. Surface Active Agents
B-1: Surfadone
®
LP-100 (N-octyl pyrrolidone)
B-2: Surfadone
®
LP-300 (N-dodecyl pyrrolidone)
♦ High surface activity at low concentrations:
LP-100 (28 dynes/cm at 0.12%)
LP-300 (26 dynes/cm at 20ppm)
♦ Synergism with anionic surfactants
♦ Low foaming and rapid wetting
♦ Biodegradable
C. Water-Soluble Polymers
C-1: PVP (Poly N-vinyl pyrrolidone)
♦ Soluble in water and many organic solvents
♦ Stabilizes emulsions, dispersions & suspensions
♦ Highly effective dye-complexing agent
♦ Viscosity modifier for aqueous systems
C-2: Gantrez
®
(Methyl vinyl ether / Maleic Anhydride Copolymer)
♦ Highly soluble in water
♦ Stable in acidic and alkaline conditions
♦ Effective binder for zinc, calcium and magnesium ions
♦ Surface active in aqueous solution
♦ Dispersing, coupling and stabilizing properties
♦ Thickener for aqueous and organic solvent
C-3: Antara
®
430 (N-vinyl pyrrolidone and Styrene Copolymer)
(Antara 430 is marketed as Polectron
®
in the U.S.)
♦ Opacifier of thermoplastic latex
♦ Excellent mechanical and chemical stability
♦ Forms transparent, thermoplastic films
♦ Broad compatibility with other lattices
D. Biocides
D-1: Integra
®
44 (Aqueous sodium hydroxymethyl glycinate)
♦ Broad spectrum antimicrobial activity
♦ Effective against bacteria and fungi
♦ Active from pH 3.5 to 12
♦ EPA registered
6
3 Hand Soap Formulations
3.10 Liquid Hand Soap
Formulation
Ingredients Weight %
01. Sodium lauryl ether sulphate 70% paste
02. Surfadone® LP-300 (ISP)
03. Empigen® BB
04. Sodium Chloride
05. Integra® 44 (ISP)
06. Dye
07. Fragrance
08. Water
09. Citric acid
15.00
1.00
2.00
1.50
0.15
q.s.
q.s.
up to 100
to pH 7.0
Formulation Instructions
1. Dissolve sodium lauryl ether sulphate, Surfadone LP-300 and Empigen BB in water.
2. Add NaCl. Adjust pH to 6.5~7.0 with citric acid or caustic soda.
3. Add Integra 44, dye and fragrance.
Suppliers
01 Sodium lauryl ether sulphate 70% paste Huntsman, Rhodia
03 Empigen BB (Lauryl dimethyl betaine) Huntsman, Rhodia
02, 05 Surfadone LP-300, Integra 44 ISP
Others Dye, fragrance and Sodium Chloride Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
7
4 Laundry Cleaning Formulations
4.10 Laundry Pre-Spotter
Formulation
Ingredients Weight %
01. Unisan
®
SS5053
02. Gantrez
®
AN 149 (ISP)
03. Nonylphenol ethoxylate (9EO)
04. Surfadone
®
LP-100 (ISP)
05. M-Pyrol
®
Solvent (ISP)
06. Sodium tripolyphosphate
07. Integra
®
44 (ISP)
08. Dye
09. Fragrance
10. Water
6.20
0.50
1.00
0.50
3.00
0.50
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Dissolve Unisan SS5053 in water.
2. Add Gantrez AN 149 and sodium tripolyphosphate, stir until all dissolved.
3. Add nonylphenol ethoxylate (9EO), Surfadone LP-100, n-methyl pyrrolidone (M-Pyrol)
and Integra 44 and mix until homogeneous.
4. Add dye and fragrance.
Suppliers
01. Unisan SS5053 (sodium alkyl benzene sulphonate 50% paste) Huntsman, Rhodia
03. Nonylphenol ethoxylate 9EO Huntsman, Rhodia
06. Sodium tripolyphosphate Rhodia, Haifa
02, 04 Gantrez AN 149, Surfadone LP-100 ISP
05, 07 M-Pyrol, Integra 44 ISP
Others Dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
8
4 Laundry Cleaning Formulations
4.11 Laundry Pre-Spotter & Stain Remover
Formulation
Weight % Ingredients
Formula A Formula B
01. Surfadone
LP-100 (ISP) 2 4
02. Gafac BX-660 (80%, Rhodia) 4 ---
03. Tetrapotassium Pyrophosphate 4 ---
04. Ammonium Hydroxide (28%) 8 1
05. Isopropanol 8 2
06. Dipropylene Glycol Monomethyl Ether 2 10
07. Perchloroethylene --- 22
08. Alipal HP-433 (Rhodia) --- 40
09. Triethanolamine --- 5
10. Water 72 17
Formulation Instructions
1. Charge water to a clean, dry vessel.
2. Add remaining raw materials in the order shown and mix until homogenous.
Performance Data
The above formulae were tested for stain removal ability versus a commercial European pre-wash on
pre-stained 65/35 polyester/cotton swatches. For the commercial pre-wash, label use instructions
were followed prior to laundering. The soiled test swatches were evaluated after pre-treatment only,
not after machine laundering. The percent removal was estimated visually after rinsing with water.
% Stain Removal
Stain Type Commercial Brand Formula A Formula B
Wine 20 60 85
Chocolate Pudding 20 40 75
Motor Oil 5 15 75
Lipstick 5 70 60
Grass / Humus / Blood 0 40 20
Blood 0 0 0
The test results & formulations above show that Surfadone LP-100 can provide performance superior to
a contemporary solvent pre-wash product. This superior performance can be obtained with or without
chlorinated solvents, demonstrating that Surfadone can be used to develop solvent-free formulas.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
9
4 Laundry Cleaning Formulations
4.20 Liquid Laundry Detergent (Clear & non-builder)
Formulation
Ingredients Weight %
01. Unisan
SS5053
02. Tinopal
CBS-X (Optical brightener)
03. Sodium lauryl ether sulphate 70% paste
04. Nonylphenol ethoxylate (9EO)
05. Surfadone
LP-100 (ISP)
06. PVP K-30 (ISP)
07. Soda ash
08. Integra
44 (ISP)
09. Dye
10. Fragrance
11. Water
25.60
0.05
15.00
3.00
1.00
0.50
1.00
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Dissolve Unisan SS5053 in water.
2. Add Tinopal CBS-X, soda ash and PVP K-30.
3. Add sodium lauryl ether sulphate, nonylphenol ethoxylate 9EO and Surfadone LP-100,
stir until all ingredients are dissolved.
4. Add Integra 44, dye and fragrance.
Suppliers
01. Unisan SS5053 (Sodium alkyl benzene sulphonate Huntsman, Rhodia
02. Tinopal CBS-X (Optical brightener) Ciba
03. Sodium lauryl ether sulphate 70% paste Huntsman, Rhodia
04. Nonylphenol ethoxylate 9EO Huntsman, Rhodia
05, 06, 08 Surfadone LP-100, PVP K-30 and Integra 44 ISP
Others: Soda ash, dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
10
4 Laundry Cleaning Formulations
4.21 Heavy Duty Liquid Laundry Detergent
Formulation
Ingredients Weight %
Part A
01. Unisan
SS 5053
02. Lauryl alcohol ethoxylate (7EO) or KB7
03. Surfadone
LP-100 (ISP)
04. PVP K-30 (ISP)
05. Gantrez
AN 149 (ISP)
06. Glycerin
07. Water
Part B
08. Sodium sulphate
09. Sodium tripolyphosphate
10. Antara
430 (Polectron) (ISP)
11. Integra
44 (ISP)
12. Water
14.00
2.00
1.00
0.50
1.00
7.20
26.00
0.70
22.0
0.50
0.15
25.00
Formulation Instructions
Part A
1. Dissolve Unisan SS-5053 in water
2. Add KB7, LP-100, PVP K-30, Gantrez AN 149 and glycerin
Part B
1. Dissolve sodium sulphate and sodium tripolyphosphate in water
2. Mix part A and B, followed by Integra 44 and Antara (Polectron) 430
Suppliers
01 Unisan SS 5053 (sodium alkyl benzene sulphonic 50% paste) Rhodia, Huntsman
02 Lauryl alcohol ethoxylate (KB7) Huntsman, Rhodia
06 Glycerin Kao, Henkel
03, 04, 05 Surfadone LP-100, PVP K-30, Gantrez AN-149 ISP
10, 11 Antara 430 and Integra 44 ISP
08, 09 Sodium sulphate and sodium tripolyphosphate Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
11
4. Laundry Cleaning Formulations
4.30 Powder Laundry Detergent (Color-Safe)
Formulation
Ingredients Weight %
01 NaPAS or NaLAS Surfactant 6.34
02 Nonionic Surfactant 7EO 14.26
03 Hardened tallow soap 2.21
04 Zeolite MAP (anhydrous basis) 40.14
05 Sodium citrate (2aq) 21.93
06 Sodium carbonate (light) 1.26
07 Sodium carboxymethylcellulose (70%) 0.98
08 EDTMP (DEQUEST
2047) 1.43
09 Protease (SAVINASE
6.0T 1635 GU/mg) 1.20
10 Lipase (LIPOLASE
100T 287 LU/mg) 0.28
11 Amylase (TERMAMYL *60T 4.3 MU/mg) 0 or 0.06
12 Antifoam granule 3.15
13 Fragrance 0.45
14 CHROMABOND
S-100 or S-400 (ISP) 0.03 - 1.0
15 Minor other additives to 100.00
Powder Bulk density 800-900 g/l
Formulation Instructions
See Instructions in Formulation Reference: Research Disclosure, July 1998, Number 41175
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
12
4. Laundry Formulations
4.40 Laundry Detergent Tabs (Formula #1)
Formulation
Ingredients Weight %
Base Powder
01. Sodium linear alkylbenzene sulfonate
02. C
13-15
fatty alcohol 7EO
03. C
13-15
fatty alcohol 3EO
04. Soap
05. Zeolite A24
06. Sodium acetate trihydrate
07. Sodium carbonate
08. Sodium Carboxymethylcellulose
09. Moisture & impurities
Laundry Tab Formula
10. Base Powder (see composition above)
11. Sodium percarbonate granules
12. TAED granules
13. Anti-foam granules
14. Perfume, enzymes, etc.
15. HPA tripolyphosphate
16. DISINTEX-600 (ISP disintegrating agent)
17. Sodium carbonate
20.8
6.0
3.2
1.6
46.4
5.9
6.9
0.9
8.3
45.0
15.0
3.4
3.2
3.5
20.0
2-5
balance to 100.0
Formulation Instructions
1. Prepare base powder with ingredients listed above.
2. Mix base powder and remaining tab formula ingredients in a V-mixer for 30 minutes.
3. Press mixed powder at 2.4 Tons pressure using dry compression to make 40 gr tablets.
(lab tabs were pressed with Carver Automated Press at 100 psi and 1sec. dwell time)
4. Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm
until complete dissolution enabled tab granules to pass through a metal gauze cage.
Reference: Patents WO 98/55590, WO 00/32741
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
13
4. Laundry Formulations
4.41 Laundry Detergent Tabs (Formula #2)
Formulation
Ingredients Weight %
Base Powder
01. C
25
Alkylethoxy 5
02. Glucose Amide
03. Zeolite A
04. Sodium carbonate
05. DISINTEX-600 (ISP-tab disintegrating agent)
06. Moisture, others
Laundry Tab Formula
10. Base Powder (see above list of ingredients)
11. Percarbonate
12. NaSKS-6
13. Carbonate
14. Polycarbonate
15. Sulfate
16. Zeolite A
17. NaAS
18. NaAE3S
19. Na LAS
20. TAED
21. Citric acid monohydrate
22. Enzymes
23. Optical Brightener
24. SOREZ-100 (ISP – soil release agent)
25. Carboxymethylcellulose (soil anti-redeposition)
26. Perfume, others
18.0
6.0
50.0
8.0
10.0
8.0
20.0
18.0
11.0
7.0
3.0
6.0
11.0
7.0
2.0
1.0
5.0
3.0
1.0
0.25
0.5
0.35
1.0
Formulation Instructions
1 Prepare base powder with ingredients listed above.
2 Mix base powder and remaining tab formula ingredients in a V-mixer for 30 minutes.
3 Press mixed powder at 2.4 Tons pressure using dry compression to make 40 gr. tablets.
(lab tabs were pressed using a Carver Automated Press at 100 psi and 1sec. dwell time)
4 Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until
complete dissolution enabled tab granules to pass through a metal gauze cage.
Reference: Patent - WO 99/36493
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
14
4. Laundry Cleaning Formulations
4.50 Fabric Softener (3 Formulations)
Formulation
Weight % Ingredients
Formula A Formula B Formula C
01. Adogen
442
02. Arquad
2HT-75
03. Integra
44 (ISP)
04. Surfadone
LP-100 (ISP)
05. Surfadone
LP-300 (ISP)
06. Dye
07. Fragrance
08. Water
6.70
-
0.15
0.50
-
q.s.
q.s.
up to 100
6.70
-
0.15
-
1.0
q.s.
q.s.
up to 100
-
6.67
0.15
-
0.30
q.s.
q.s.
up to 100
Formulation Instructions
1. Warm Adogen 442 to 55°C, then add into water and stir well at 55°C.
2. Cool to 35°C.
3. Add Surfadone, Integra 44, fragrance and dye.
Suppliers
01 Adogen 442 Goldschmidt
02 Arquad 2HT-75 Akzo Nobel
03, 04, 05 Surfadone LP-100, LP-300 and Integra 44 ISP
06, 07 Dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
15
5 Dishwashing Formulations
5.10 Manual Liquid Dishwash Detergent
Formulation
Ingredients Weight %
01. Deionized Water 70.00
02. Dodecyl Benzene Sulphonic Acid (DDBSA) 10.50
03. Sodium Hydroxide (50%) 3.00
04. Sodium Lauryl Sulphate (29%) 13.00
05. Lauryl Dimethyl Amine oxide (30%) 2.00
06. Surfadone
LP-100 (ISP) 1.50
07. Fragrance, Dye, Preservative etc. q.s.
Formulation Instructions
1. Charge the mixing vessel with water, and commence stirring.
2. Add the DDBSA while mixing and SLOWLY add the sodium hydroxide solution.
(Caution - this is an exothermic reaction. Cool the mixing vessel if necessary)
3. Check & adjust the pH to neutral with either more sodium hydroxide or phosphoric acid,
as needed.
4. While stirring, add the remaining ingredients in the order given and mix until homogenous.
Suppliers
02 Nansa SSA Albright & Wilson Americas
04 Empicol LX28 Albright & Wilson Americas
05 Ammonyx LO Stepan
06 Surfadone LP-100 ISP
07 Fragrance, dye, preservatives Local supplier
Additional Formulation Information
Detergency is provided by a blend of DDBS and SLS surfactants.
Amine oxide acts as a foam stabilizer / booster, and may in addition help to reduce the skin
irritation potential of the DDBS.
Surfadone LP-100 improves the wetting performance of the aqueous solution, aids the
penetration and solubilization of greasy soils and in conjunction with the other surfactants
increases the viscosity of the product, removing the need for electrolyte or thickeners.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
16
5 Dishwashing Formulations
5.11 Liquid Dishwash Detergent (Formula #1)
Formulation
Ingredients Weight %
01. Alkyl benzene sulphonic acid (LABSA)
02. Caustic soda 50%
03. Sodium lauryl ether sulphate 70%
04. Coco/diethanol amide
05. Surfadone
LP-300 (ISP)
06. Sodium Chloride
07. Integra
44 (ISP)
08. Dye
09. Lemon Fragrance
10. Citric acid
11. Water
9.80
2.55
5.80
1.00
1.00
0.40
0.15
q.s.
q.s.
to pH 7.0
up to 100
Formulation Instructions
1. Add caustic soda to water.
2. Add alkyl benzene sulphonic acid, stir until all neutralized.
3. Add sodium lauryl ether sulphate, coco-diethanol amide and Surfadone LP-300, and
stir until all ingredients are dissolved.
4. Add Integra 44, dye, lemon and citric acid.
5. Add sodium chloride.
Suppliers:
01. Alkyl benzene sulphonic acid (LABSA) LG Chemicals, Rhodia
03. Sodium lauryl ether sulphate 70% paste Rhodia, Huntsman
04. Coco-diethanol amide Huntsman, Henkel
05, 07 Surfadone LP-300 and Integra 44 ISP
Others Caustic soda, sodium chloride, dye, fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
17
5 Dishwashing Formulations
5.12 Liquid Dishwash Detergent (Formula #2)
Formulation
Ingredients Weight %
01. SLES - Sodium lauryl ether sulphate (70%)
02. Coconut diethanolamine
03. Surfadone
LP-300 (ISP)
04. Sodium Chloride
05. Integra
44 (ISP)
06. Dye
07. Fragrance
08. Citric acid to pH 7.0
09. Water
15.0
1.0
1.0
2.5
0.15
q.s.
q.s.
q.s.
up to 100
Formulation Instructions
1. Charge the water into the vessel.
2. Add SLES, stir with mechanical stirrer until all dissolved.
3. Add coconut diethanolamine and Surfadone LP-300, stir until all dissolved.
4. Add Integra 44, dye and fragrance, stir all until homogeneous.
5. Add Sodium Chloride
6. Adjust pH to 6.8~7.0 with citric acid (or caustic soda).
Suppliers:
01 Sodium lauryl ether sulphate (70%) Rhodia
02 Coconut diethanolamine Rhodia
03, 05 Surfadone LP-300 and Integra 44 ISP
04, 07, 08 NaCl, Citric acid, dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
18
5 Dishwashing Formulations
5.15 Ecological Liquid Dishwash Detergent
Formulation
Ingredients Weight %
01. Sodium lauryl ether sulphate 70%
02. Empigen BB (lauryl dimethyl betaine)
03. Empilan KB9 (lauryl alcohol eth25oxylate (9EO))
04. Empigen OB (lauryl dimethyl amine oxide)
05. Surfadone
LP-100 (ISP)
06. Sodium Chloride
07. Integra
44 (ISP)
08. Dye
09. Lemon Fragrance
10. Citric acid
11. Water
16.9
6.5
1.0
3.5
1.0
1.0
0.15
q.s.
q.s.
to pH 7
up to 100
Formulation Instructions
1. Charge water to the vessel.
2. Add SLES stir until all dissolved.
3. Add Empigen BB, Empilan KB9 and Empigen OB, stir until all dissolved.
4. Add Integra 44, dye and lemon fragrance.
5. Add NaCl.
6. Adjust pH to 6.8~7.0 with citric acid or NaOH.
Suppliers
01 Sodium lauryl ether sulphate 70% Rhodia, Huntsman
02 Empigen BB (lauryl dimethyl betaine) Huntsman, Kao
03 Empilan KB9 (lauryl alcohol ethoxylate (9EO)) Huntsman, Rhodia
04 Empigen OB (lauryl dimethyl amine oxide) Huntsman, Rhodia
05, 07 Integra 44, Surfadone LP-100 ISP
06, 09, 10 NaCl, citric acid, dye and lemon Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
19
5 Dishwashing Formulations
5.20 Automatic Liquid Dishwash Detergent
Formulation
Ingredients Weight %
01. Eltesol SX pellets (sodium xylene sulphonate)
02. Sodium metasilicate
03. Empilan KA590 (C9-11 alcohol ethoxylate (5EO, 90%)
04. Surfadone
LP-100 (ISP)
05. Potassium hydroxide (pellets)
06. Gantrez
AN 169 (ISP)
07. EDTA
08. Tetrapotassium pyrophosphate
09. Isopropyl alcohol
10. Integra
44 (ISP)
11. Dye
12. Fragrance
13. Water
6.5
4.0
1.0
1.0
3.0
0.85
0.15
15.0
3.0
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Dissolve Eltesol SX pellet, sodium metasilicate, KOH, EDTA and tetrapotassium
pyrophosphate in water.
2. Add Empilan KA 590, Surfadone LP-100 and Gantrez AN-169.
3. Add isopropyl alcohol, and the remaining ingredients, stir until clear.
Suppliers
01 Eltesol SX pellet (Sodium xylene sulphonic pellet) Huntsman
03 Empilan KA 590 (C9-11 alcohol ethoxylate (5EO) 90% liquid) Huntsman
04, 06, 10 Surfadone LP-100, Gantrez AN 169 and Integra 44 ISP
Others EDTA, KOH, Tetrapotassium Pyrophosphate,
Isopropyl Alcohol, Dye, Fragrance, Sodium Metasilicate Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
20
5 Dishwashing Formulations
5.30 Dishwash Detergent Tablets
Formulation
Ingredients Weight %
Base Powder
01. STTP
02. Sodium Carbonate
03. Sodium Sulfate
04. Sodium Metasilicate
05. Sodium Sterate
06. C13-15 fatty alcohol 9EO
Dishwashing Tab Formula
07. Base Powder (see composition above)
08. DISINTEX-200 Disintegrating Aid (ISP)
40.0
32.8
19.3
6.4
0.8
0.7
98.0
2.0
Formulation Instructions
1. Prepare base powder with ingredients listed above.
2. Mix base powder and Disintex-200 disintegrating agent in a V-mixer for 30 minutes.
3. Press mixed powder at 11 tons pressure using dry compression to make 20 gr. tablets.
(lab tabs were pressed using a Carver Automated Press at 387 psi and 1 sec. Dwell time)
4. Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until
complete dissolution enabled tab granules to pass through a metal gauze cage.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
21
5 Dishwashing Formulations
5.50 Automatic Dishwash Rinse Aid (Formula #1)
Formulation
Ingredients Weight %
01. Deionized water 79.00
02. Synperonic LFRA 30 12.00
03. Synperonic LFRA 260 3.00
04. Surfadone
LP-100 (ISP) 2.00
05. Sodium Cumene Sulphonate (40%) 4.00
06. Dye, Preservative, etc. q.s.
Formulation Instructions
1. Charge the mixer with the deionized water and commence stirring.
2. Add the ingredients in the order listed above with stirring, mix until homogeneous.
Note: The level of Sodium Cumene Sulphonate has been selected to give a cloud point
of around 45
o
C, but this can be altered by changing the level of SCS used.
Suppliers
02. Synperonic LFRA 30 ICI Surfactants Americas
03. Synperonic LFRA 260 ICI Surfactants Americas
04. Surfadone LP-100 ISP
05 Eltesol SC40 Albright & Wilson Americas
Formulation Information
The two Synperonic LFRA surfactants (Fatty Alcohol EO/PO adducts of proprietary formula)
have been selected to give a blend of wetting and defoaming properties. The blend properties
can be altered by varying the ratio of wetting (LFRA 30) & defoaming (LFRA 260) ingredients.
Surfadone LP-100 acts in combination with the nonionic blend to greatly reduce the surface
tension of the formulation when dispersed in aqueous solution, and hence improve the
potential of this solution to form a continuous thin film on the surface of the rinsed items. This
in turn reduces the drying time, and helps to reduce the amount of streaking and smearing
seen on the dried articles. Surfadone LP-100 has no effect on the amount of foaming caused
by the formulation.
Sodium Cumene Sulphonate acts as a Hydrotrope, to ensure that the cloud point of the
formulation is high enough to prevent separation occurring under warm conditions.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
22
5 Dishwashing Formulations
5.51 Automatic Dishwash Rinse-Aid (Formula #2)
Formulation
Ingredients Weight %
01. Empilan PF7158 (alcohol-ethoxylate-propoxylate copolymer)
02. Surfadone
LP-100 (ISP)
03. Citric acid
04. Isopropyl alcohol
05. Eltesol SX pellet (sodium xylene sulphonate)
06. Integra
44 (ISP)
07. Dye
08. Fragrance
09. Water
30.0
2.5
8.0
8.0
1.5
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Charge water into the vessel.
2. Add Eltesol SX and citric acid, stir until dissolved.
3. Add Empilan PF7158 and Surfadone LP-100, stir until dissolved.
4. Add isopropyl alcohol.
5. Add Integra 44, dye and fragrance.
Suppliers:
01 Empilan PF7158 (alcohol-ethoxylate-propoxylate copolymer) Huntsman, Rhodia
05 Eltesol SX pellet (sodium xylene sulphonate pellet) Huntsman, Huls
02, 06 Surfadone LP-100, Integra 44 ISP
Others Isopropyl alcohol, citric acid, dye, fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
23
6 Household Cleaning Formulations
6.10 Multi-purpose Hard Surface Cleaner
Formulation
Ingredients Weight %
01. LABSA (Linear alkyl benzene sulphonic acid)
02. Caustic soda 50%
03. Surfadone
LP-100 (ISP)
04. M-Pyrol
Solvent (ISP)
05. Integra
44 (ISP)
06. Dye
07. Fragrance
08. Water
6.0
1.5
1.5
1.0
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Charge water into the vessel.
2. Add caustic soda 50%.
3. Add LABSA, stir until all dissolved.
4. Add Surfadone LP-100, M-Pyrol, Integra 44, dye and fragrance.
Suppliers:
01. LABSA (Linear alkyl benzene sulphonic acid) Rhodia, LG Chemical
03, 04, 05 Surfadone LP-100, M-Pyrol, Integra 44 ISP
02, 06, 07 Caustic soda, dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
24
6 Household Cleaning Formulations
6.20 Multipurpose Alkaline Degreaser
Formulation
Ingredients Weight %
01. Tetrapotassium pyrophosphate
02. Surfadone
LP-300 (ISP)
03. LABSA (Linear alkyl benzene sulphonic acid)
04. Caustic soda 50%
05. Eltesol SX pellet
06. M-Pyrol
Solvent (ISP)
07. Integra
44 (ISP)
08. Dye
09. Fragrance
10. Water
5.0
1.0
1.5
0.5
4.5
2.0
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Charge water into the vessel.
2. Add caustic soda, followed by LABSA, stir until all neutralized.
3. Add tetrapotassium pyrophosphate, Eltesol SX pellet, stir until dissolved.
4. Add Surfadone LP-300, stir until all dissolved.
5. Add the remaining components and stir well to homogeneous.
Suppliers:
01 Tetrapotassium pyrophosphate Rhodia
03 LABSA (Linear alkyl benzene sulphonic acid) Rhodia, Huntsman
05 Eltesol SX pellet (Sodium xylene sulphonate) Huntsman
02, 06, 07 Surfadone LP-300, M-Pyrol, Integra 44 ISP
08, 04, 09 Dye, Caustic Soda and Fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
25
6 Household Cleaning Formulations
6.21 Kitchen Disinfectant Cleaner
Formulation
Ingredients Weight %
01. Empigen BAC 80 (benzalkonium 80%)
02. Surfadone
LP-100 (ISP)
03. Tetrapotassium pyrophosphate
04. Ethylene diamine tetraacetate, sodium salt (EDTA)
05. Dye
06. Fragrance
07. Water
2.0
1.5
3.0
0.2
q.s.
q.s.
up to 100
Formulation Instructions
1. Charge water into the vessel.
2. Add tetrapotassium pyrophosphate and EDTA, stir until all dissolved.
3. Add Empigen BAC 80, stir until homogeneous.
4. Add Surfadone LP-100, stir until dissolved.
5. Add dye and fragrance.
Suppliers
01 Empigen BAC 80 Huntsman
02. Surfadone LP-100 ISP
03. Tetrapotassium pyrophosphate Rhodia
04, 05, 06 EDTA, dye & fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
26
6. Household Cleaning Formulations
6.22 Kitchen Degreaser (Formula #1)
Formulation
Ingredients Weight %
01. SLES (Sodium lauryl ether sulphate 70%)
02. Surfadone
LP-100 (ISP)
03. Surfadone
LP-300 (ISP)
04. Propylene glycol methyl ether
05. M-Pyrol
Solvent (ISP)
06. EDTA
07. Integra
44 (ISP)
08. Blue dye
09. Fragrance
10. Water
1.0
0.3
0.1
3.0
3.0
3.0
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Charge water into the vessel.
2. Add EDTA, stir until all dissolved.
3. Add SLES, stir until all dissolved.
4. Add Surfadone LP-100 and 300.
5. Add the remaining component and stir until homogeneous.
Suppliers:
01. SLES (Sodium lauryl ether sulpahte 70%) Huntsman, Henkel
04. Propylene glycol methyl ether Dow and Lyodell
02, 03 Surfadone LP-100, Surfadone LP-300 ISP
06, 07 M-Pyrol and Integra 44 ISP
Others EDTA, dye, fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
27
6 Household Cleaning Formulations
6.23 Kitchen Degreaser (Formula #2)
Formulation
Ingredients Weight %
01. Deionized Water 87.65
02. Sodium Lauryl Ether Sulphate (27%) 2.50
03. C
13
Alcohol / 9EO 0.75
04. Propylene Glycol Methyl Ether 3.00
05. M-Pyrol
®
Solvent (ISP) 3.00
06. Na
3
NTA (38%) 3.00
07. Surfadone
LP-300 (ISP) 0.10
08. Dye, Fragrance, Preservative etc. q.s.
Formulation Instructions
1. Introduce the water and commence stirring.
2. Add the SLES with stirring.
3. Add the alcohol ethoxylate. Stir until homogenous.
4. Add the remaining ingredients with stirring.
Suppliers
02 Empimin KSN27 Albright and Wilson Americas
03 Synperonic 13/8 ICI Surfactants Americas
04 Dowanol PM Dow
05, 07 M-Pyrol, Surfadone LP-300 ISP
08 Na
3
NTA, dye, fragrance, preservative Local Supplier
Additional Formulation Information
The two surfactants provide a range of detergency properties - wetting, foaming etc. The nonionic
is particularly effective on oils and greases, providing soil removal and emulsification properties
and helping to prevent redeposition.
Surfadone LP-300 acts in conjunction with the surfactants, improving the wetting properties, and
aiding the penetration of the surfactants into the soils. The solvents increase the cleaning effect by
helping to dissolve hydrophobic soils. The glycol ethers offer anti-redeposition properties.
The complexing agent (NTA) improves the tolerance of the formulation (particularly the anionic
surfactant) to the presence of water hardness ions. In addition, it improves the cleaning effect,
notably on particulate soils.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
28
6 Household Cleaning Formulations
6.24 Kitchen Degreaser (Formula #3)
Formulation
Ingredients Weight %
01. Deionized Water 87.65
02. Sodium Lauryl Ether Sulphate (27%) 2.50
03. C
13
Alcohol / 9EO 0.75
04. Propylene Glycol Methyl Ether 3.00
05. M-Pyrol
Solvent (ISP) 3.00
06. Na
4
EDTA (38%) 3.00
07. Surfadone
LP-300 (ISP) 0.10
08. Dye, Fragrance, Preservative etc. q.s.
Formulation Instructions
1. Introduce the water and commence stirring.
2. Add the SLES with stirring.
3. Add the alcohol ethoxylate. Stir until homogenous.
4. Add the remaining ingredients with stirring.
Suppliers
02 Empimin KSN27 Albright & Wilson Americas
03 Synperonic 13/8 ICI Surfactants Americas
04 Dowanol PM Dow
05, 07 M-Pyrol, Surfadone LP-300 ISP
06, 08 Na
4
EDTA, Dye, Fragrance, Preservative Local Supplier
Additional Formulation Information
The two surfactants provide a range of detergency properties - wetting, foaming etc. The
nonionic is particularly effective on oils and greases, providing soil removal and emulsification
properties and helping to prevent redeposition.
Surfadone LP-300 acts in conjunction with the surfactants, improving the wetting properties,
and aiding surfactant penetration into the soils. The solvents increase the cleaning effect by
helping to dissolve hydrophobic soils. The glycol ethers offer anti-redeposition properties.
The complexing agent (EDTA) improves the tolerance of the formulation (particularly the
anionic surfactant) to the presence of water hardness ions. In addition, it improves the
cleaning effect, notably on particulate soils.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
29
6 Household Cleaning Formulations
6.25 Oven Cleaner
Formulation
Ingredients Weight %
01. Deionized Water 72.30
02. M-Pyrol
Solvent (ISP) 20.00
03. Gantrez
S97-BF (ISP) 0.50
04. C
9-11
Alcohol / 8EO (Synperonic 918) 2.00
05. Surfadone
LP-300 (ISP) 0.20
06. Monoethanolamine 5.00
Formulation Instructions
1. Charge the mixing vessel with the water, and commence stirring.
2. Premix Gantrez S97-BF in some M-Pyrol to form slurry, and add to mixer.
3. Use the remaining M-Pyrol to rinse the premix vessel into the mixer, to ensure that all the
Gantrez S97-BF is added.
4. Add the Alcohol Ethoxylate and Surfadone LP-300 with stirring.
5. Finally add Monoethanolamine. The neutralization of the acidic functionalities causes the
polymer to swell, resulting in a clear, viscous solution.
6. Continue stirring to ensure the polymer becomes fully hydrated.
Suppliers
04 Synperonic 918 ICI Surfactants Americas
02, 03, 05 M-Pyrol, Gantrez S97-BF, Surfadone LP-100 ISP
06 Monoethanolamine Local Supplier
Additional Formulation Information
Surface activity is provided by the combination of the nonionic surfactant and the Surfadone
LP-300, giving the formulation the ability to wet greasy surfaces. Surfadone LP-300 has also
the ability to penetrate into oily and greasy soils, thus helping to dislodge them from the
surfaces.
Once in solution, the M-Pyrol, Surfadone LP-300 and the nonionic surfactant in combination
with the alkalinity from the MEA act to solubilize and emulsify the soils to leave a clean
surface.
Gantrez S97-BF is present to add viscosity to the formulation, helping it to “cling” to the
surfaces being cleaned and hence maximize the contact time.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
30
6 Household Cleaning Formulations
6.26 Kitchen Cleaning Wipes
Formulation
Ingredients Weight %
01. Deionized Water
02. Isopropyl Alcohol (IPA)
03. M-Pyrol® Solvent (ISP)
04. Surfadone® LP-100 (ISP)
05. Sodium Cocoyl Glutamate
06. Sodium Hydroxide (10% aqueous solution)
07. Integra® 44 (ISP)
08. Fragrance
91.65
2.00
2.00
1.50
1.50
1.18
0.15
0.02
Formulation Instructions
1. Add the ingredients in the order listed, stirring thoroughly after each addition.
2. Apply to wipe substrate in a 1:1 weight ratio.
Suppliers
03, 04, 07 M-Pyrol, Surfadone LP-100, Integra-44 ISP
Others IPA, Sodium Cocoyl Glutamate, NaOH, fragrance Local Supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
31
6 Household Cleaning Formulations
6.30 Glass Cleaner (Formula #1)
Formulation
Ingredients Weight %
01. Surfadone
LP-100 (ISP)
02. Dipropylene glycol methyl ether
03. Isopropyl alcohol
04. Integra
44 (ISP)
05. Dye
06. Water
0.15
1.0
9.0
0.15
q.s.
up to 100
Formulation Instructions
1. Mix all components and stir mixture until homogeneous.
Suppliers:
02. Dipropylene glycol methyl ether Lyondell, Dow
01, 04 Surfadone LP-100 and Integra 44 ISP
03, 05. Isopropyl alcohol (IPA) and Dye Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
32
6 Household Cleaning Formulations
6.31 Glass Cleaner (Formula #2)
Formulation
Ingredients Weight %
01. Deionized Water 90.79
02. Isopropanol alcohol (IPA) 5.00
03. Propylene Glycol Methyl Ether 4.00
04. Magnesium Lauryl Ether Sulphate (27%) 0.02
05. Monoethanolamine 0.15
06. Ammonia (28%) 0.15
07. Surfadone
LP-300 (ISP) 0.01
08. Fragrance, Dye, Preservative, etc. q.s.
Formulation Instructions
1. Charge the mixing vessel with the water, and commence stirring.
2. Add the remaining ingredients with stirring in the order given above.
Suppliers
03. Dowanol PM Dow
04. Empicol EGC Albright & Wilson Americas
07. Surfadone LP-300 ISP
Others IPA, PG/ME, MLES, Monoethanolamine, etc Local Supplier
Additional Formulation Information
Isopropyl alcohol and glycol ether give the volatility necessary for fast drying.
MgLES aids wetting of the surface. Tests show that the magnesium salts are more efficient than
the corresponding sodium salts in reducing the amount of streaking or smearing. Nitrogenous
buffers (in this case MEA) also help in this regard. Ammonia as a co-buffer aids removal of
greasy soils, and is also easily volatilized, promoting streak-free appearance.
Surfadone LP-300 acts as a co-solvent for removing greasy soils, and in addition promoting the
solubility of fragrances where necessary. The tremendous wetting power of Surfadone LP-300 in
conjunction with the anionic enables excellent coverage of the surface to be achieved whilst using
very low levels of non-volatile components - reducing the amount of smearing and streaking.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
33
6 Household Cleaning Formulations
6.32 Glass Cleaning Wipes
Formulation
Ingredients Weight %
01. Deionized Water
02. Isopropyl Alcohol (IPA)
03. Dipropylene Glycol Methyl Ether
04. Integra® 44 (ISP)
05. Surfadone® LP-100
89.70
9.00
1.00
0.15
0.15
Formulation Instructions
1. Add the ingredients in the order listed, stirring thoroughly after each addition.
2. Spray onto wipes and package in air-tight containers.
Suppliers
04, 05 Integra 44, Surfadone LP-100 ISP
Others IPA, Dipropylene Glycol Methyl Ether Local Supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
34
6 Household Cleaning Formulations
6.40 Bathroom Cleaner (Formula #1)
Formulation
Ingredients Weight %
01. Deionized Water
02 Lauryl Dimethyl Amine oxide (30%)
03 Glycolic Acid (65%)
04 Acetic Acid (Glacial)
05 Alkyl Dimethyl Benzyl Ammonium Chloride (50%)
06 Surfadone
LP-100 (ISP)
07 Fragrance, Dye, Preservative etc.
89.60
2.00
3.00
1.50
1.40
2.50
q.s.
Formulation Instructions
1. Charge the mixing vessel with the water and commence stirring.
2. Add the remaining ingredients with stirring in the order given above.
Suppliers
02. Ammonyx LO Stepan
05. Empigen BAC Albright & Wilson Americas
06. Surfadone LP-100 ISP
Others Glycolic Acid, Acetic Acid, etc. Local Supplier
Additional Formulation Information
The acidic nature of the formulation aids in the break-down and dissolution of hardness salt
based soils, such as limescale and soap scum.
Detergency and surface activity are provided by the combination of the amine oxide and
Sufadone LP-100. The amine oxide also acts as a coupler for the formulation - it has been
found that if the amount of coupler used is increased to more than is actually necessary to
solubilize the other ingredients, a remarkable increase in the cleaning ability of the formulation
is observed.
It has also been observed that the Surfadone LP100 has the ability to reduce soap scum
deposition on surfaces.
The quaternary ammonium chloride is present to give the formulation a bactericidal effect.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
35
6 Household Cleaning Formulations
6.41 Bathroom Cleaner (Formula #2)
Formulation
Ingredients Weight %
01. Deionized Water
02. Sodium Lauryl Sulphate (29%)
03. C
9-11
Alcohol / 8EO
04. Phosphoric Acid (85%)
05. Surfadone
LP-100 (ISP)
06. Citric Acid Monohydrate
07. Glycolic Acid (65%)
08. Magnesium Sulphate Heptahydrate
09. Fragrance
10. Dye, Preservative etc.
to 100
13.00
3.00
0.10
0.025
1.50
3.50
1.50
0 - 1.0
q.s.
Formulation Instructions
1. Charge the mixing vessel with the water and commence stirring.
2. Add the anionic and nonionic surfactants, and stir until completely dispersed.
3. Add the remaining ingredients, except the Fragrance, with stirring.
4. Adjust the pH to 3.0 (Use NaOH if required)
5. Stir in the Fragrance to form a clear microemulsion.
Suppliers
02. Empicol LX28 Albright & Wilson Americas
03. Synperonic 918 ICI Surfactants Americas
05. Surfadone LP-100 ISP
Others All other ingredients Local Supplier
Additional Formulation Information
Detergency is provided by the blend of nonionic and anionic surfactants. The acidic nature of the
formulation aids in the break down and dissolution of hardness salt based soils, such as limescale and
soap scum.
The combination of phosphoric acid, carboxylic acid and Surfadone LP100 protects certain surfaces
from acid etching. It is suggested that a complex forms, which can attach to negatively charged
surfaces and hence reduce acid attack. Surfadone LP100 addition reduces the soap scum deposition
on surfaces.
The inclusion of magnesium ions and the fragrance are necessary to enable a microemulsion
to form. The levels of the two can be varied - in addition the type of fragrance used will also affect the
amount required for the microemulsion to form. It has also been suggested that the inclusion of a small
amount of magnesium ions improves the cleaning efficiency of the product, particularly in soft water
areas.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
36
6 Household Cleaning Formulations
6.42 Toilet Bowl Cleaner
Formulation
Weight % Ingredients
Formula A Formula B
01. Deionized Water 71.0 74.4
02. Mulgofen ON-870 (Rhodia) 1.0 0.6
03. Gantrez
AN-169 (ISP) 3.0 2.0
04. Hydrochloric Acid (37%) 25.0 23.0
Viscosity (cps)
1200
130
Formulation Instructions
1. Charge water to a clean, dry vessel.
2. Add Mulgofen ON-870 to the water and mix until homogenous.
3. Add Gantrez AN-169 slowly to the water/surfactant mix and heat to 70-80°C.
Stir until a thick gel results. (Note: Make up any water loss and cool to 40°C.)
4. Add the hydrochloric acid and mix well until homogenous.
Suppliers
02. Mulfogen ON-870 Rhodia
03. Gantrez AN-169 ISP
04. Hydrochloric Acid Local Supplier
Additional Formulation Information
The acidic nature of the formulation aids in the breakdown of hardness salt based soils, such
as limescale and soap scum.
The Gantrez AN:ethoxylated surfactant partial ester imparts thickening emulsion and freeze-
thaw stability and surface activity to aid in the cleaning ability of the formulation. The ester
complex of Gantrez AN will not form if the order of addition is reversed.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
37
6 Household Cleaning Formulations
6.50 Floor Cleaner
Formulation
Ingredients Weight (%)
Part A
01. Unisan SS5053
02. Water
Part B
03. Antara
430 (Polectron) (ISP)
04. Water
Part C
05. Sodium tripolyphosphate
06. Nonylphenol ethoxylate 9EO
07. Integra
44 (ISP)
08. Dye
09. Fragrance
5.10
81.80
0.10
9.55
1.00
2.30
0.15
q.s.
q.s.
Formulation Instructions
1. Part A: Dissolve Unisan SS5053 in water.
2. Part B: Disperse Antara 430 in water.
3. Part C: Mix Parts A, B and C well.
Suppliers
01. Unisan SS5053 (Sodium alkylbenzene sulphonate 50% paste) Huntsman, Rhodia
03, 07 Antara 430 (Polectron), Integra-44 ISP
05. Sodium tripolyphosphate Rhodia
06. Nonylphenol ethoxylate 9EO Huntsman, Rhodia
08, 09 Dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
38
6 Household Cleaning Formulations
6.51 Floor Polish (2 Formulations)
Formulation
Weight % Ingredients
Formula A Formula B
01. Surfactant FC-120
02. Surfadone
LP-300 (ISP)
03. Wacker SRE
04. Ethylene glycol methyl ether
05. Dipropylene glycol methyl ether
06. 2-Pyrol
Solvent (ISP)
07. M-Pyrol
Solvent (ISP)
08. Dibutyl phthalate
09. Tributoxy ethyl phosphate
10. Integra
44 (ISP)
11. Primal B-924
12. Primal E-1531
13. Michem ME 39235
14. Water
0.04
0.03
0.10
1.00
3.34
1.20
-
1.13
1.13
0.15
37.31
5.92
7.59
up to 100
0.04
0.03
0.10
1.00
3.34
-
1.20
1.13
1.13
0.15
37.31
5.92
7.59
up to 100
Formulation Instructions
1. Mix chemicals in the following order: Water, Surfactant FC-120, Surfadone LP-300,
Wacker SRE, Ethylene glycol methyl ether, Dipropyl glycol methyl ether, 2-Pyrol or
M-Pyrol, Dibutyl phthalate, Tributoxy ethyl phosphate and Integra 44. Agitate for a
few minutes.
2. Slowly add Primal B-924 with constant stirring and continue to stir for 30 minutes.
3. Slowly add Primal E-1531 with constant stirring and continue to stir for 10 minutes.
4. Slowly add Michem ME 39235 with constant stirring and continue to stir for 1 hour.
5. Allow standing for a day before use.
Suppliers
01. Surfactant FC-120 3M, Ciba
02,06,07,10 Surfadone LP-300, 2-Pyro, M-Pyrol, Integra-44 ISP
03. Wacker SRE (defoamer) Wacker, Dow Corning
04. Ethylene glycol methyl ether Dow (Union Carbide)
05. Dipropylene glycol methyl ether Dow (Union Carbide)
08. Dibutyl phthalate Eastman
09. Tributoxy ethyl phosphate Rhodia, FMC
11. Primal B-924 (acrylic binder) Rohm & Haas
12. Primal E-1531 (alkali soluble resin) Rohm & Haas
13. Michem ME 39235 (wax emulsion) Michelman
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation to
practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
39
6 Household Cleaning Formulations
6.52 Carpet Cleaner
Formulation
Ingredients Weight %
01. Sodium lauryl sulphate
02. Coco/diethanol amide
03. Surfadone
LP-100 (ISP)
04. Isopropyl alcohol
05. Integra
44 (ISP)
06. Dye
07. Fragrance
08. Water
10.00
2.00
1.00
10.00
0.15
q.s.
q.s.
up to 100
Formulation Instructions
1. Dissolve sodium lauryl sulphate in water.
2. Add coco/diethanolamide, isopropyl alcohol and Surfadone LP-100.
3. Add Integra 44, dye and fragrance, mix until homogenous.
Suppliers
01. Sodium lauryl sulphate Huntsman, Henkel
02. Coco-diethanol amide Huntsman, Henkel
03, 05 Surfadone LP-100 and Integra 44 ISP
04, 06, 07 Isopropyl alcohol, dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
40
6 Household Cleaning Formulations
6.53 Machine Carpet Cleaner
Formulation
Ingredients Weight %
01. Eltesol SX 40 (sodium xylene sulphonate 40%)
02. Surfadone
LP-100 (ISP)
03. Tetrapotassium Pyrophosphate
04. Butyl Carbitol
05. EDTA 38%
06. Integra
44 (ISP)
07. Dye
08. Fragrance
09. Phosphoric acid (85%)
10. Water
6.50
1.00
7.50
8.00
0.50
0.15
q.s.
q.s.
to pH 7
up to 100
Formulation Instructions
1. Dissolve all solids in water.
2. Then add the remaining ingredients and mix until homogenous.
Suppliers
01. Eltesol SX 40 (sodium xylene sulphonate 40%) Huntsman
02, 06 Surfadone LP-100 and Integra 44 ISP
04. Butyl Carbitol Dow, Huntsman
Others Tetrapotassium pyrophosphate, phosphoric acid
EDTA, dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
41
6 Household Cleaning Formulations
6.55 Silicone Furniture Polish
Formulation
Ingredients Weight %
01. KELGIN HV (ISP)
02. Mineral Spirits
03. Carnauba Wax
04. Cardis 319 Wax
05. Paraffin Wax
06. SF96-300 Silicone Fluid
07. Span 60
08. Tween 60
09. Dowcide A (preservative)
10. Water
0.30
20.00
1.00
1.50
2.50
4.00
1.50
1.50
0.10
up to 100
Formulation Instructions
1. Dissolve KELGIN HV in cold water with gradual addition and good agitation.
2. Take the KELGIN HV solution and add Dowcide A and Tween 60.
3. Heat a mixture of all other ingredients to 170 F.
4. Heat the Kelgin solution (Step 1) to 170 F.
5. Mix hot solutions from Steps 3 and Step 4 until homogeneous.
Suppliers
01. Kelgin HV (Sodium Alginate thickener) ISP
04. Cardis 319 Wax Warwick Wax Company
06. SF96-300 Silicone Fluid General Electric
07, 08 Span 60, Tween 60 (emulsifying agents) Atlas Powder Company
09. Dowcide A (preservative) Dow Chemical
02, 03, 05 Mineral Spirits, Carnauba Wax & Paraffin Wax Local supplier
Additional Formulation Information
Kelgin HV is a refined industrial grade of sodium alginate, which is a valuable ingredient to all
types of liquid polishes. This excellent thickening, stabilizing and suspending agent, provides
the following important properties:
♦ Ease of Solution in either hot or cold water, without any prolonged period of hydration;
♦ Uniformity to assure superior and dependable thickening performance;
♦ Improved Stability for most finished polish formulations;
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
42
6 Household Cleaners
6.60 Windscreen Cleaner
Formulation
Ingredients Weight %
01. Dipropylene glycol methyl ether
02. M-Pyrol
Solvent (ISP)
03. Surfadone
LP-100 (ISP)
04. Isopropyl alcohol
05. Silwet 7608 (Silicone surfactant)
06. Integra
44 (ISP)
07. Dye
08. Water
6.0
10.0
1
10.0
0.2
0.15
q.s.
up to 100
Formulation Instructions
1. Mix all components, stir until homogeneous.
Suppliers
01. Dipropylene glycol methyl ether Dow, Lyondell
05. Silwet 7608 (silicone surfactant) Crompton
03, 02, 06 Surfadone LP-100, M-Pyrol, Integra 44 ISP
04, 07 Isopropyl alcohol, dye Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
43
6 Household Cleaners
6.70 Air Freshener (Formula #1)
Formulation
Ingredients Weight %
01. Isopropyl alcohol
02. Surfadone
LP-300 (ISP)
03. Lemon fragrance
04. Dye (Green)
05. Integra
44 (ISP)
06. Water
5.00
0.10
2.00
q.s.
0.15
up to 100
Formulation Instructions
1. Add isopropyl alcohol, and Surfadone LP-300 to the lemon fragrance.
2. Add water, followed by dye and Integra 44.
Suppliers
02, 05 Surfadone LP-300 and Integra 44 ISP
01, 03, 04 Isopropyl Alcohol, lemon fragrance and dye Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
44
6 Household Cleaners
6.71 Air Freshener (Formula #2 - Poppy Fragrance)
Formulation
Ingredients Weight %
Phase A
01. Water
02. Preservative
03. Sodium Hexametaphosphate (Calgon)
Phase B
04. Glycerine
05. Manugel GHB (ISP)
Phase C
06. Poppy Fragrance (Independent Fragrance Company)
07. Polysorbate 80
Phase D
08. Water
09. Calcium Sulphate Dihydrate (Terra Alba)
10. Sodium Hexametaphosphate (Calgon)
69.250
q.s.
0.060
5.000
2.000
20.000
1.000
1.700
0.340
0.150
Formulation Instructions
1. Phase A: Dissolve Phase A Calgon in water and add then add preservative.
2. Phase B: Slurry Manugel GHB alginate in glycerine and add to Phase A with mixing.
Mix for 10-15 minutes until alginate thickener is fully hydrated.
3. Phase C: Mix the poppy fragrance and the Polysorbate 80 solubilizer.
Add Phase C to Phase AB with high speed mixing until homogenized.
4. Phase D: Dissolve the Phase D Calgon in the water and then slurry the Terra Alba.
5. Inject Phase D into Phase ABC and mix with high shear for 10 seconds.
6. Place into suitable containers and leave to set for at least four hours.
Suppliers
03. Sodium Hexametaphosphate (Calgon) Calgon Corporation
05. Manugel GHB (Alginate) ISP
06. Poppy Fragrance Independent Fragrance Company
Others All other ingredients Local Supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
45
7 Industrial & Institutional Cleaners
7.10 Car Wash Shampoo
Formulation
Weight % Ingredients
Non-Wax Wax
01. Triethanolamine salt of alkyl benzene sulphonic acid (TS-6053)
02. Surfadone
LP-300 (ISP)
03. Coco/diethanol amide
04. Integra 44 (ISP)
05. M-Pyrol
Solvent (ISP)
06. Dye
07. Fragrance
08. Water
30.00
2.00
2.00
0.15
-
q.s.
q.s.
up to 100
30.00
2.00
2.00
0.15
2
q.s.
q.s.
up to 100
Formulation Instructions
1. Dissolve TS 6053, Coco-diethanol amide and Surfadone LP-300 in water.
2. Add the M-Pyrol solvent.
3. Add Integra 44, dye and fragrance.
Suppliers
01. Triethanolamine salt of alkyl benzene sulphonic acid Huntsman, Stepan
03. Coco-diethanol amide Huntsman, Henkel
02, 04, 05 Surfadone LP-300, Integra 44 and M-Pyrol ISP
06, 07 Dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
46
7 Industrial & Institutional Cleaners
7.11 Car Wash & Wax Cleaner
Formulation
Weight % Ingredients
Non-Wax Wax
01. Triethanolamine salt of alkyl benzene sulphonic acid (TS 6053)
02. Surfadone
LP-300 (ISP)
03. Coco/diethanol amide
04. Integra
44 (ISP)
05. Carnauba wax
06. M-Pyrol
Solvent (ISP)
07. Dye
08. Fragrance
09. Water
30.00
2.00
2.00
0.15
1.00
-
q.s.
q.s.
up to 100
30.00
1.00
1.00
0.15
1.00
2
q.s.
q.s.
up to 100
Formulation Instructions
1. Dissolve TS 6053, Coco/diethanol amide and Surfadone LP-300 in water.
2. Add carnauba wax and M-Pyrol.
3. Add Integra 44, dye and fragrance.
Suppliers
01. Triethanolamine salt of alkyl benzene sulphonic acid Huntsman, Stepan
03. Coco/diethanol amide Huntsman, Henkel
05. Carnauba wax Bronson & Jacob
02, 04, 06 Surfadone LP-300, Integra 44 and M-Pyrol ISP
07, 08 Dye and fragrance Local supplier
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
47
7 Industrial & Institutional Cleaners
7.12 High Gloss Tire Wax
Formulation
Ingredients Weight %
01. L45 (350 cts)
02. L45 (1000 cts)
03. Surfadone
LP-300 (ISP)
04. Emulsifier
05. Antara
430 (ISP)
06. Gantrez
AN 169 (ISP)
07. Water
25.00
5.00
0.50
6.00
1.00
0.80
up to 100
Formulation Instructions
1. Add emulsifier and Surfadone LP-300 to L45, mix well
2. Add Antara 430, Gantrez AN 169 and water, mix well.
Suppliers
01, 02 Dimethicone 350 cts and 1000 cts (L45) Crompton, Dow Corning
04. Emulsifier Mutiara Chemical Trading
03, 05, 06 Surfadone LP-300, Antara 430, Gantrez AN 169 ISP
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
48
7 Industrial & Institutional Cleaners
7.13 Liquid Car Polish
Formulation
Ingredients Weight %
01. Light Mineral Oil
02. Carnauba Wax
03. Glycerine
04. Celite 315
05. Calgon
06. KELGIN HV (ISP)
07. Dowcide A (preservative)
08. Pluronic L44
09. Water
16.00
1.40
4.10
10.20
0.20
0.50
0.13
0.67
up to 100
Formulation Instructions
1. Dissolve KELGIN HV in cold water by gradual addition and good agitation.
2. Take the KELGIN HV solution and add Calgon, Pluronic L44, Dowcide A and Glycerine.
3. Add Celite 315 to the liquid mixture and heat up to 140 F.
4. In another container, dissolve the carnauba wax in mineral oil.
5. Add the hot liquid mixture of Step 3 slowly to the Step 4 solution with good agitation.
6. Cool the resulting product, pass through a colloid mid and package.
Suppliers
04. Cellite 315 (diatomaceous earth) Johns-Manville Corp.
05. Calgon Calgon Corporation
06. Kelgin HV (Sodium Alginate thickener) ISP
07. Dowcide A (preservative) Dow Chemical
08. Pluronic L44 (emulsifying agent) BASF
01, 02, 03 Light Mineral Oil, Carnauba Wax & Glycerine Local supplier
Additional Formulation Information
Various simple modifications of the above formula should produce a polish which would
satisfy all product requirements. Durability of the polished film may be changed with the type
of abrasive used together with wax constituent variations. The gloss of the polished film may
be enhanced with the addition of silicone oil, variation of the wax constituent, or variations in
the oil content. Finally, drying time may be altered by the addition of mineral spirits.
The percentage of KELGIN HV required should remain relatively constant for most
modifications of the given formula, but in a few cases it may be necessary to alter the quantity
slightly to obtain the desired results. It is suggested that the 0.5% level is tried first and then,
if necessary, altered in the direction indicated.
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
49
7 Industrial & Institutional Cleaners
7.20 Alkaline Grill Cleaner
Formulation
Ingredients Weight %
01. Caustic soda 50%
02. Gantrez
AN 149 (ISP)
03. Mackam OAB
04. Water
20.00
1.00
1.00
up to 100
Formulation Instructions
1. Add caustic soda to water.
2. Add Mackam OAB, followed by Gantrez AN 149.
Suppliers
01. Caustic soda (50%) Local supplier
02. Gantrez AN 149 ISP
03. Mackam OAB (Amine oxide stable in acid) McIntyre, Rhodia
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
50
7 Industrial & Institutional Cleaners
7.30 Metal Cleaner
Formulation
Ingredients Weight %
01. Phosphoric acid 85%
02. M-Pyrol
Solvent (ISP)
03. Water
12.00
4.00
up to 100
Formulation Instructions
1. Add acid to M-Pyrol and water with continuous stirring.
2. A slight exothermic reaction will occur.
3. Mix all ingredients until you have a homogenous cleaner solution.
Suppliers
01. Phosphoric acid (85%) Rhodia
02. M-Pyrol® Solvent ISP
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
51
Appendix A: Summary of Chemical Functionalities
Chemical names Functionalities
01 Caustic soda or NaOH pH adjuster
02 Alkyl benzene sulphonates.
Alkali earth salts
Dispersant, detergency and foaming
03 Sodium lauryl ether sulphonate Emulsifier, surfactant (shampoo), textile auxilliary
04 Sodium lauryl sulphate Emulsifier, foaming agent, wetting agent
05 Methanol Co-solvent
06 Coconut acid diethanolamide Foam booster, stabilizer, emulsifier, thickener
07 NaCl Filler, salting-out reagent
08 Citric acid Buffering agent, pH adjuster
09 Nonylphenol ethoxylate Emulsifier, surfactant, wetting agent, defoaming agent
10 Lauryl alcohol ethoxylate Emulsifier
11 Glycerol or glycerin Humectant, solvent
12 Sodium tripolyphosphate Detergent builder, softening agent
13 Adogen/quaternary ammonium salts Emulsifier, dispersant, softener, antistat
14 Silwet or dimethicone copoly Surfactant, dispersant, emulsifier, leveling agent
15 IPA Disinfectant
16 Sodium xylene sulphonate Hydrotrope (heavy duty detergent)
17 Empilan or ethoxylate ether\ester Emulsifier, foamer, wetting agent, dispersant
18 EDTA Chelating agent, metal deactivator, anti-oxidant
19 Phosphoric acid Etchant, acidulant
20 Tetrasodium pyrophosphate Detergent builder, sequesterant
21 Triethanolamine alkylbenzene
sulphonate
Pigment dispersant, surfactant, dry cleaning
detergent
22 Carnauba wax Car, floor or shoe polish, paraffin wax modifier
23 Dimethyl lauryl amine oxide Foam booster, stabilizer
24 Sodium metasilicate Detergent builder, stabilizer of peroxide bleach
25 Briquest or phosphonic acid Powder detergent, peroxide stabilizer, scale inhibitor
26 Benzalkonium chloride Disinfectant
27 Propylene glycol monomethyl ether Coalescing solvent
28 Hexylene glycol Solvent
29 Dipropylene glycol Solvent
30 Soda Ash or sodium carbonate Neutralizing agent, pH adjuster
31 Tinopal Fluorescent whitening agent
32 Arquat/quaternary ammonium salts Emulsifier, foaming agent, wetting agent, softener
33 Acusol or acrylic acid Thickener, detergent polymer, emulsion stabilizer,
suspending agent
34 Mackam or sulfosuccinate uSurfactant
35 Ethylene glycol methyl ether Solvent
36 Dibutyl phthalate Plasticizer
37 Tributoxy ethyl phosphate Coalescing solvent, antifoamer
38 Primal Pigment dispersant
The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied
as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation
to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.
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Tel: 1 630 932-4022
Toll Free: 1 (800) 323-2272
Fax: 1 630 495-0245
[email protected]
VENEZUELA
Tel: + 58 212 991-4545
+ 58 212 992-9703
+ 58 212 991-7775
Fax: + 58 212 991-9705
[email protected]
MEXICO
Tel: + 52 55 5589-0721
Fax: + 52 55 5589-7345
[email protected]
COLOMBIA
Tel: + 57 (1) 638-6203
Fax: + 57 (1) 616-3030/6030
[email protected]
BRAZIL
Tel: + 55 11 3649-0469
Fax: + 55 11 3835-4212
[email protected]
ARGENTINA
Tel: + 54 11 4314-8971/0659/
3293
Fax: + 54 11 4314-8976
[email protected]
TAIWAN
Tel: +8862 2508-0212
Fax: +8862 2504-3543
[email protected]
THAILAND
Tel: +662 267-8103
Fax: +662 236-0041
[email protected]
KOREA
Tel: +822 554-6622/6934
Fax: +822 554-6944
[email protected]
MALAYSIA
Tel: +603 5513-1448/28/98
Fax: +603 5512-8311
[email protected]
PHILIPPINES
Tel: +632 848-7188
Fax: +632 848-7191
[email protected]
SINGAPORE
Tel: +656 223-3778
Fax: +656 226-0853
[email protected]
MUMBAI, INDIA
Tel: +9122 2837-0472
Tel: +9122 2839-2624
Tel: +9122 2837-0449
[email protected]
INDONESIA
Tel: +6221 530-7181/82
Fax: +6221 530-7183
[email protected]
OSAKA, JAPAN
Tel: +816 6838-5544
Fax: +816 6838-5566
[email protected]
TOKYO, JAPAN
Tel: +813 5566-8661
Fax: +813 5566-8682
[email protected]
GUANGZHOU, CHINA
Tel: +8620 3758-9970
Fax: +8620 3758-9907
[email protected]
SHANGHAI, CHINA
Tel: +8621 6249-3900
Fax: +8621 6249-3908
[email protected]
HONG KONG
Tel: +852 2881-6108
Fax: +852 2895-1250
[email protected]
HYDERABAD, INDIA
Tel: +9140 2335-1009
Fax: +9140 2335-1009
[email protected]
N.S.W. AUSTRALIA
Tel: +612 9648-5177
Fax: +612 9647-1608
[email protected]
VICTORIA, AUSTRALIA
Tel: +613 9899-5082
Fax: +613 9899-5102
[email protected]
BEIJING, CHINA
Tel: +8610 6515-6265
Fax: +8610 6515-6267
[email protected]
CHENGDU, CHINA
Tel: +8628 8557-1040
Fax: +8628 8557-2313
[email protected]
INTERNATIONAL SPECIALTY PRODUCTS
™ Trademark registration applied for ® Registered trademark of the ISP group © International Specialty Products. 2002 Designed & Printed in USA.
The information contained in this brochure and the various products described are intended for use only by persons having technical skill and at their own discretion and risk after they have performed necessary technical investi-
gations, tests and evaluations of the products and their uses. While the information herein is believed to be reliable, we do not guarantee its accuracy and a purchaser must make its own determination of a product’s suitability for
purchaser’s use, for the protection of the environment, and for the health and safety of its employees and the purchasers of its products. Neither ISP nor its affiliates shall be responsible for the use of this information, or of any
product, method, or apparatus described in this brochure. Nothing herein waives any of ISP’s or its affiliates’ conditions of sale, and WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY
PRODUCT FOR A PARTICULAR USE OR PURPOSE. We also make no warranty against infringement of any patents by reason of purchaser’s use of any information, product, method or apparatus described in this brochure.
USA & CANADA REGIONAL SALES OFFICES
LATIN AMERICA CUSTOMER SERVICE
EUROPE & AFRICA CUSTOMER SERVICE
ASIA PACIFIC CUSTOMER SERVICE
Product Code HI&I Formulation Guide 5/2003
